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    新型TSADA的合成及其土壤重金属污染修复行为

    Synthesis of new-type TSADA and its remediation behavior for soil heavy metal pollution

    • 摘要: 为提高茶皂素(TS)修复土壤重金属离子的能力,经水提沉淀法从茶籽饼提取茶皂素,以其为原料设计合成新型绿色茶皂素基螯合剂(茶皂素-1-酰胺二乙烯三胺,TSADA),用FTIR研究TSADA的结构,并对其表面性能进行研究。结果表明,其临界胶束浓度低于茶皂素,而亲水亲油平衡值、起泡力及稳泡性均优于茶皂素。同时考察了振荡时间、螯合剂浓度、pH值及离子强度对螯合剂去除污染土壤重金属率的影响,发现,TSADA去除重金属率随振荡时间、浓度的增加而升高,随pH值和离子强度的增加而降低。螯合剂去除Pb2+、Cd2+离子的最佳工艺为:振荡时间为12h,质量分数为7%,pH值为5.0,Ca(NO3)2浓度为10mmol/L。此条件下2种螯合剂对土壤中Pb2+、Cd2+离子去除率均达最大,TSADA对Pb2+和Cd2+离子去除率均优于茶皂素;TSADA对Pb2+和Cd2+离子的最大去除率分别为67.3%和99.9%。

       

      Abstract: In order to improve remediation ability of tea-saponin for heavy metal ions in the soil, the new-type green tea-saponin chelant(tea-saponin-1-amide-diethylenetriamine, TSADA) was prepared by tea saponin raw material extracted through aqueous extract-alcohol precipitation from tea seed cake. TSADA’s structure was studied by FT-IR, and its superficial performance was studied as well. Results showed that its critical micelle concentration was lower than the TS’s, but Hydrophile-lipophile Balance value and foaming and stable foam ability were higher than TS’s. Meanwhile the effect of some factors such as oscillation time, chelating agent concentration, pH and ionic strength on removal rate of heavy metal ions in contaminated soil by chelate was investigated. The results showed that the removal rate of heavy metal ions increased with oscillation time, chelating agent concentration increasing, reduced with ionic strength and pH increasing. The optimum technologies of removing Pb2+,Cd2+ ions by chelating agent were as follows: Oscillation time was 12h, chelating agent mass concentration was 7%, pH was 5.0, mole concentration of Ca(NO3)2 was 10mmol/L. Under the conditions, removal rate of Pb2+ and Cd2+ ions in the soil by two chelating agents both reached the maximum. Removal rate of Pb2+ and Cd2+ ions by TSADA was better than tea saponin’s respectively. The maximum removal rate of Pb2+ and Cd2+ ions by TSADA was 67.3% and 99.9% respectively.

       

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